Gogotsi Y. MXenes. From Discovery to Applications...2023
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Textbook in PDF format Since their discovery in 2011, MXenes (2D carbides, nitrides, and carbonitrides of early transition metals) have developed into one of the largest and most intensively studied families of 2D materials. They offer unique properties and are being explored in a large variety of applications. This book compiles the most important research from a pioneer of the field, Professor Yury Gogotsi, and his interdisciplinary research team, as well as numerous collaborators worldwide. It reports on the discovery and rise of MXenes and describes their synthesis and processing, properties, and incorporation into polymer, ceramic, and metal matrices to produce composites. It also discusses the potential of MXenes for use in energy storage, optics, electronics, and sensing, as well as biomedical, environmental, and electrocatalysis applications. The book will appeal to anyone interested in nanomaterials and their synthesis, properties, and applications. The Rise of MXenes Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2 Two-Dimensional Transition Metal Carbides Two-Dimensional, Ordered, Double Transition Metals Carbides Synthesis of Two-Dimensional Titanium Nitride Ti4N3 Synthesis of Mo4VAlC4 MAX Phase and Two-Dimensional Mo4VC4 MXene with Five Atomic Layers of Transition Metals Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides Elastic Properties of 2D Ti3C2Tx MXene Monolayers and Bilayers Control of MXenes’ Electronic Properties through Termination and Intercalation High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis Electrochromic Effect in Titanium Carbide MXene Thin Films Produced by Dip-Coating Effects of Synthesis and Processing on Optoelectronic Properties of Titanium Carbonitride MXene Raman Spectroscopy Analysis of the Structure and Surface Chemistry of Ti3C2Tx MXene Intercalation and Delamination of Layered Carbides and Carbonitrides Conductive Two-Dimensional Titanium Carbide ‘Clay’ with High Volumetric Capacitance Amine-Assisted Delamination of Nb2C MXene for Li-Ion Energy Storage Devices Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide Selective Etching of Silicon from Ti3SiC2 (MAX) to Obtain 2D Titanium Carbide (MXene) Additive-Free MXene Inks and Direct Printing of Micro-Supercapacitors Additive-Free MXene Liquid Crystals and Fibers Scalable Manufacturing of Free-Standing, Strong Ti3C2Tx MXene Films with Outstanding Conductivity Scalable Synthesis of Ti3C2Tx MXene Flexible and Conductive MXene Films and Nanocomposites with High Capacitance Flexible MXene/Graphene Films for Ultrafast Supercapacitors with Outstanding Volumetric Capacitance Cold Sintered Ceramic Nanocomposites of 2D MXene and Zinc Oxide Colloidal Gelation in Liquid Metals Enables Functional Nanocomposites of 2D Metal Carbides and Lightweight Metals MXene: A Promising Transition Metal Carbide Anode for Lithium-Ion Batteries Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide 2D Metal Carbides and Nitrides for Energy Storage Ultra-High-Rate Pseudocapacitive Energy Storage in Two-Dimensional Transition Metal Carbides Thickness-Independent Capacitance of Vertically Aligned Liquid-Crystalline MXenes High Capacity Silicon Anodes Enabled by MXene Viscous Aqueous Ink Influences from Solvents on Charge Storage in Titanium Carbide MXenes Charge- and Size-Selective Ion Sieving through Ti3C2Tx MXene Membranes Single Platinum Atoms Immobilized on an MXene as an Efficient Catalyst for the Hydrogen Evolution Reaction MXene Molecular Sieving Membranes for Highly Efficient Gas Separation MXene Sorbents for Removal of Urea from Dialysate: A Step toward the Wearable Artificial Kidney A Gel-Free Ti3C2Tx-Based Electrode Array for High-Density, High-Resolution Surface Electromyography Electromagnetic Interference Shielding with 2D Transition Metal Carbides 2D Titanium Carbide for Wireless Communication Metallic Ti3C2Tx MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio Surface-Modified Metallic Ti3C2Tx MXene as Electron Transport Layer for Planar Heterojunction Perovskite Solar Cells Anomalous Absorption of Electromagnetic Waves by 2D Transition Metal Carbonitride Ti3CNTx Beyond Ti3C2Tx: MXenes for Electromagnetic Interference Shielding